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  5. AI-guided design of cyclic peptide binders targeting TREM2 using CycleRFdiffusion and experimental validation

AI-guided design of cyclic peptide binders targeting TREM2 using CycleRFdiffusion and experimental validation

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File(s)
41435973.pdf (1.42 MB)
No Access Until
2027-12-21
Permanent Link(s)
https://hdl.handle.net/1813/124369
Collections
Department of Radiology
Author
Cho, S.
Zhu, R.
Kuncewicz, K.
Duan, H.
Gabr, M.
Abstract

Triggering receptor expressed on myeloid cells 2 (TREM2) plays a central role in regulating microglial function in the central nervous system and has emerged as a promising therapeutic target for Alzheimer's disease. Despite advances in antibody-based therapeutics, small molecules and peptides capable of modulating TREM2 remain limited. Here, we present a cyclic peptide design pipeline that integrates CycleRFdiffusion, ProteinMPNN for sequence design, and HighFold for structural prediction and screening. Using the TREM2 structure as input, we generated and screened 1500 peptide-target complexes, prioritizing four candidates that met structural and energetic criteria. Subsequent biophysical evaluation identified TP4 as a weak but reproducible TREM2 binder, demonstrating consistent binding in spectral shift, microscale thermophoresis, and surface plasmon resonance. Pharmacokinetic profiling indicated that TP4 possesses favorable plasma stability and moderate metabolic stability, supporting its potential for further optimization. This study establishes a generalizable framework for AI-driven cyclic peptide discovery and provides the first proof-of-concept demonstration of TREM2-targeted cyclic peptide binders.

Journal / Series
Bioorganic & medicinal chemistry letters
Volume & Issue
133
Date Issued
2025-12-21
Publisher
Elsevier
Keywords
WCM Library Coordinated Deposit
•
Receptors, Immunologic/metabolism/antagonists & inhibitors/chemistry
•
Peptides, Cyclic/chemistry/pharmacology/chemical synthesis/metabolism
•
Humans
•
Membrane Glycoproteins/metabolism/antagonists & inhibitors/chemistry
•
Drug Design
•
Structure-Activity Relationship
•
Molecular Structure
•
Alzheimer's disease
•
Biophysical screening
•
Computational chemistry
•
Peptides
•
Trem2
Related DOI
https://doi.org/10.1016/j.bmcl.2025.130512
Previously Published as
Cho S, Zhu R, Kuncewicz K, Duan H, Gabr M. AI-guided design of cyclic peptide binders targeting TREM2 using CycleRFdiffusion and experimental validation. Bioorganic & medicinal chemistry letters. 2025;133:130512. doi: 10.1016/j.bmcl.2025.130512. PMID: 41435973.
Rights
Attribution-NonCommercial-NoDerivatives 4.0 International
Rights URI
https://creativecommons.org/licenses/by-nc-nd/4.0/
Type
article

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