Cornell University
Library
Cornell UniversityLibrary

eCommons

Help
Log In(current)
  1. Home
  2. Cornell Centers, Laboratories, Institutes, Projects and Programs
  3. KAUST - Cornell Center for Energy and Sustainability
  4. Energy and Sustainability Publications
  5. High Resolution Shear Profile Measurements in Entangled Polymers

High Resolution Shear Profile Measurements in Entangled Polymers

File(s)
High Resolution Shear Profile Measurements in Entangled Polymers.pdf (309.6 KB)
Permanent Link(s)
https://hdl.handle.net/1813/33446
Collections
Energy and Sustainability Publications
Author
Hayes, K.A.
Buckley, M.R.
Cohen, I.
Archer, L.A.
Abstract

We use confocal microscopy and particle image velocimetry to visualize motion of 250-300 nm. fluorescent tracer particles in entangled polymers subject to a rectilinear shear flow. Our results show linear velocity profiles in polymer solutions spanning a wide range of molecular weights and number of entanglements (8< or =Z< or =56), but reveal large differences between the imposed and measured shear rates. These findings disagree with recent reports that shear banding is a characteristic flow response of entangled polymers, and instead point to interfacial slip as an important source of strain loss.

Sponsorship
This study was supported by the National Science Foundation (DMR0551185 and DMR0606040) and by KAUST-CU Center for Energy and Sustainability. We are grateful to Erik Herz and Ulrich Wiesner for providing fluorescent nanoparticle tracers used in the study.
[
Date Issued
2008-11-17
Publisher
Physical Review Letters
Keywords
entangled polymers
•
interfacial slip
Previously Published as
Phys Rev Lett. 2008 Nov 21;101(21):218301. Epub 2008 Nov 17.
Type
article

Site Statistics | Help

About eCommons | Policies | Terms of use | Contact Us

copyright © 2002-2026 Cornell University Library | Privacy | Web Accessibility Assistance