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  5. Aseembly of Vorticity-Aligned Hard-Sphere Colloidal Strings in a Simple Shear Flow

Aseembly of Vorticity-Aligned Hard-Sphere Colloidal Strings in a Simple Shear Flow

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Assembly of vorticity-aligned hard-sphere colloidal strings in a simple shear flow.pdf (1.41 MB)
Main article
Permanent Link(s)
https://hdl.handle.net/1813/33442
Collections
Energy and Sustainability Publications
Author
Cheng, X.
Xu, X.
Rice, S.A.
Dinner, A.R.
Cohen, I.
Abstract

Colloidal suspensions self-assemble into equilibrium structures ranging from face- and body-centered cubic crystals to binary ionic crystals, and even kagome lattices. When driven out of equilibrium by hydrodynamic interactions, even more diverse structures can be accessed. However, mechanisms underlying out-of-equilibrium assembly are much less understood, though such processes are clearly relevant in many natural and industrial systems. Even in the simple case of hard-sphere colloidal particles under shear, there are conflicting predictions about whether particles link up into string-like structures along the shear flow direction. Here, using confocal microscopy, we measure the shear-induced suspension structure. Surprisingly, rather than flow-aligned strings, we observe log-rolling strings of particles normal to the plane of shear. By employing Stokesian dynamics simulations, we address the mechanism leading to this out-of-equilibrium structure and show that it emerges from a delicate balance between hydrodynamic and interparticle interactions. These results demonstrate a method for assembling large-scale particle structures using shear flows

Sponsorship
X.C. and I.C. would like to acknowledge T. Beatus, J. Brady, Y.-C. Lin, J. McCoy, D. Pine, and L. Ristroph for help with experiment and useful discussions. X.X., S.A.R., and A.R.D would like to thank J. Brady, J. Morris, and J. Swan for help with the Stokesian dynamics simulations and
useful discussions. The research by X.C. and I.C. was supported by grants from the Department of Energy, Basic Energy Sciences. This publication is based on work supported in part by Award No. KUS-C1-018-02, made by King Abdullah University of Science and Technology (KAUST). X.X., S.A.R., and A.R.D.
acknowledge financial and central facilities assistance of the University of Chicago MRSEC, supported by the National Science Foundation (NSF DMRMRSEC 0820054)
Date Issued
2011-12-23
Publisher
Proceedings of the National Academy of Sciences of the United States of America
Keywords
Vorticity-Aligned
•
Colloidal Strings
•
Hard-Sphere
•
Shear Flow
Previously Published as
Xiang Cheng, Xinliang Xu, Stuart A. Rice, Aaron R. Dinner, and Itai Cohen Assembly of vorticity-aligned hard-sphere colloidal strings in a simple shear flow PNAS 2012 109 (1) 63-67; published ahead of print December 23, 2011, doi:10.1073/pnas.1118197108
Type
article

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