Nanoscale Organic Hybrid Electrolytes
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Nanoscale organic hybrid electrolytes are composed of organic-inorganic hybrid nanostructures, each with a metal oxide or metallic nanoparticle core densely grafted with an ion-conducting polyethylene glycol corona doped with lithium salt. These materials form novel solvent-free hybrid electrolytes that are particle-rich, soft glasses at room temperature; yet manifest high ionic conductivity and good electrochemical stability above 5V.
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Work on synthesis and mechanical characterization of nanoscale organic hybrid materials (NOHMs) was supported by Award No. KUS-C1-018-02, made by King Abdullah University of Science and Technology (KAUST). Our research on electrochemical characterization of NOHMs was supported by the Department of Energy Basic Energy Sciences program (Grant DE-FG02-07ER46455)). JN acknowledges support from a National Science Foundation Sustainable Materials IGERT fellowship program at Cornell.
WILEY-V C H VERLAG GMBH
RECHARGEABLE LITHIUM BATTERIES; POLYMER ELECTROLYTES; CONDUCTIVITY
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This is the pre-peer reviewed version of the following article: Nugent, J. L., Moganty, S. S. and Archer, L. A. (2010), Nanoscale Organic Hybrid Electrolytes. Advanced Materials, 22: 3677–3680. doi: 10.1002/adma.201000898, which as been published in final form at (http://onlinelibrary.wiley.com/doi/10.1002/adma.201000898/full).
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ADVANCED MATERIALS, 22 (33): 3677-+ SEPT 1 2010