Isospecific Polymerization of Racemic Epoxides: a Catalyst System for the Synthesis of Highly Isotactic Polyethers
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Abstract
A highly active bimetallic cobalt catalyst system is reported for the polymerization of racemic terminal epoxides to yield isotactic polyethers.
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We acknowledge the NSF (CHE-0809778) and the King Abdullah University of Science and Technology (KAUST; Award No. KUS-C1-018-02) for support of this research. The authors are grateful for the help of T. Mourey at Kodak for polymer molecular weight determination
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2010-03-22
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Royal Society of Chemistry
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Isospecific Polymerization; racemic epoxides
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Chemical Communications, 46, Mar 2010, 2935-2937
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