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dc.contributor.authorTomasevich, Lauraen_US
dc.date.accessioned2014-07-28T19:24:59Z
dc.date.available2019-05-26T06:01:15Z
dc.date.issued2014-05-25en_US
dc.identifier.otherbibid: 8641192
dc.identifier.urihttps://hdl.handle.net/1813/37096
dc.description.abstractEnolate alkylation is a robust method for forming carbon-carbon bonds and has been used extensively for many decades. Despite their prevalence, the characterization of enolate aggregates has not been thoroughly explored, though prior research has shown that they form highly ordered and symmetrical aggregates in solution. Scalar coupling in NMR is often used to determine the solution structure, but this method fails when the metal is bonded to quadrupolar oxygen. Structurally diverse enolates, counterions, and ligands require a flexible method for characterization. The method of continuous variation (MCV) in conjunction with 6Li, 19F, and 1H NMR spectroscopies was used to gain structural insight into the aggregation state and stability of lithium and sodium enolates and phenolates in a range of solvents.en_US
dc.language.isoen_USen_US
dc.subjectMethod of Contimuous Variationen_US
dc.subjectJob Plotsen_US
dc.subjectEnolates and Phenolatesen_US
dc.titleStructure Determination Of Alkali Metal Enolates And Phenolates Using The Method Of Continuous Variationen_US
dc.typedissertation or thesisen_US
thesis.degree.disciplineChemistry and Chemical Biology
thesis.degree.grantorCornell Universityen_US
thesis.degree.levelDoctor of Philosophy
thesis.degree.namePh. D., Chemistry and Chemical Biology
dc.contributor.chairCollum, David Ben_US
dc.contributor.committeeMemberDichtel, William Roberten_US
dc.contributor.committeeMemberGanem, Bruceen_US


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