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dc.contributor.authorDorin, Rachelen_US
dc.date.accessioned2013-09-05T15:57:04Z
dc.date.available2018-05-27T06:00:55Z
dc.date.issued2013-05-26en_US
dc.identifier.otherbibid: 8267594
dc.identifier.urihttps://hdl.handle.net/1813/34072
dc.description.abstractBlock copolymers are promising as materials for ultrafiltration membranes due to their ability to self-assemble into periodic, ordered structures on length scales of ~550 nm. Most efforts towards fabricating functional membranes from block copolymers have targeted equilibrium morphologies, which may results in a number of potential disadvantages, including a lack of porosity in the as made films, thick separation layers, or tedious transfer and post-functionalization steps. In this dissertation, nonequilibrium block copolymer structures are used in the fabrication of ultrafiltration membranes. A system containing the triblock terpolymer poly(isoprene-b-styrene-b-4vinyl pyridine) and the solvents 1,4-dioxane and tetrahydrofuran is studied in detail. Ultrafiltration membranes fabricated from this system using a combination of selfassembly and non-solvent induced phase separation are shown to have a thin, isoporous separation layer above an asymmetric substructure. The structure and performance of these membranes are characterized using techniques such as electron microscopy, permeability, and solute rejection. The formation mechanism of the nonequilibrium triblock terpolymer membranes is studied using small angle X-ray scattering and grazing incidence small-angle X-ray scattering techniques.en_US
dc.language.isoen_USen_US
dc.titleNon-Equilibrium Triblock Terpolymer Structures As Ultrafiltration Membranesen_US
dc.typedissertation or thesisen_US
thesis.degree.disciplineMaterials Science and Engineering
thesis.degree.grantorCornell Universityen_US
thesis.degree.levelDoctor of Philosophy
thesis.degree.namePh. D., Materials Science and Engineering
dc.contributor.chairWiesner, Ulrich B.en_US
dc.contributor.committeeMemberOber, Christopher Kemperen_US
dc.contributor.committeeMemberBendaniel, David J.en_US


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