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dc.contributor.authorFernandes, N.
dc.contributor.authorDallas, P.
dc.contributor.authorRodriguez, R.
dc.contributor.authorBourlinos, A.B.
dc.contributor.authorGeorgakilas, V.
dc.contributor.authorGiannelis, E.P.
dc.date.accessioned2011-05-10T13:52:00Z
dc.date.available2011-05-10T13:52:00Z
dc.date.issued2010-05-07
dc.identifier.citationNanoscale, 2010, 2 (9), 1653-1656en_US
dc.identifier.issn2040-3364
dc.identifier.other10.1039/c0nr00307g
dc.identifier.urihttps://hdl.handle.net/1813/22896
dc.descriptionhttp://pubs.rsc.org/en/Content/ArticlePDF/2010/NR/C0NR00307G/2010-06-08?page=Searchen_US
dc.description.abstractWe report for the first time an ionic fluid based on hydroxylated fullerenes (fullerols). The ionic fluid was synthesized by neutralizing the fully protonated fullerol with an amine terminated polyethylene/polypropylene oxide oligomer (Jeffamine(R)). The ionic fluid was compared to a control synthesized by mixing the parially protonated from (sodium form) of hte fullerols with the same oligomeric amine in the same ratio as in the ionic fluids (20 wt% fullerol). In the fullerol fluid the ionic bonding significantly perturbs the thermal transitions and melting/crystallization behavior of the amine. In contrast, both the normalized heat of fusion and crystallization of the amine in the control are similar to those of the neat amine consistent with a physical mixture of the fullerols/amine with minimal interactions. In addition to differences in thermal behavior, the fullerol ionic fluid exhibits a complex viscoelastic behavior intermediate between the neat Jeffamine (R) (liquid-like) and the control (solid-like).en_US
dc.description.sponsorshipThis publication is based on work supported in part by Award No. KUS-C1-018-02 made by King Abdullah University of Science and Technology (KAUST).en_US
dc.language.isoen_USen_US
dc.publisherROYAL SOC CHEMISTRYen_US
dc.subjectLIQUID-LIKE BEHAVIORen_US
dc.subjectNANOPARTICLESen_US
dc.subjectC-60en_US
dc.subjectELECTROLYTESen_US
dc.subjectSURFACESen_US
dc.subjectCONTACTSen_US
dc.titleFullerol ionic fluidsen_US
dc.typearticleen_US


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