Cornell University
Library
Cornell UniversityLibrary

eCommons

Help
Log In(current)
  1. Home
  2. Cornell Centers, Laboratories, Institutes, Projects and Programs
  3. KAUST - Cornell Center for Energy and Sustainability
  4. Energy and Sustainability Publications
  5. Dislocations and vacancies in two-dimensional mixed crystals of spheres and dimers

Dislocations and vacancies in two-dimensional mixed crystals of spheres and dimers

File(s)
Dislocations and Vacancies in Two-dimensional Mixed Crystals of Spheres and Dimmers.pdf (601.75 KB)
Permanent Link(s)
https://hdl.handle.net/1813/33445
Collections
Energy and Sustainability Publications
Author
Gerbode, S.J.
Ong, D.C.
Liddell, C.M.
Cohen, I.
Abstract

In colloidal crystals of spheres, dislocation motion is unrestricted. On the other hand, recent studies of relaxation in crystals of colloidal dimer particles have demonstrated that the dislocation dynamics in such crystals are reminiscent of glassy systems. The observed glassy dynamics arise as a result of dislocation cages formed by certain dimer orientations. In the current study, we use experiments and simulations to investigate the transition that arises when a pure sphere crystal is doped with an increasing concentration of dimers. Specifically, we focus on both dislocation caging and vacancy motion. Interestingly, we find that any nonzero fraction of dimers introduces finite dislocation cages, suggesting that glassy dynamics are present for any mixed crystal. However, we have also identified a vacancy-mediated uncaging mechanism for releasing dislocations from their cages. This mechanism is dependent on vacancy diffusion, which slows by orders of magnitude as the dimer concentration is increased. We propose that in mixed crystals with low dimer concentrations vacancy diffusion is fast enough to uncage dislocations and delay the onset of glassy dislocation dynamics.

Sponsorship
We thank Jim Sethna, Stefano Zapperi, Fernando Escobedo, Umang Agarwal, Carl Franck, Stephanie Lee, Erin Riley, and the Cohen group for helpful discussions. This research was supported in part by the Department of Energy, Basic Energy Sciences, Grant No. ER46517 fabrication of colloidal assemblies and manipulation with optical trap and in part by Award No. KUS-C1-018-02 from King Abdullah University of Science and Technology KAUST .
Date Issued
2010-10-15
Publisher
Physical Review E
Keywords
Colloidal crystals
•
Vacancey motion
Previously Published as
Phys Rev E Stat Nonlin Soft Matter Phys. 2010 Oct; 82(4 Pt 1):041404. Epub 2010 Oct 15
Type
article

Site Statistics | Help

About eCommons | Policies | Terms of use | Contact Us

copyright © 2002-2026 Cornell University Library | Privacy | Web Accessibility Assistance