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  4. In situ observation of magnesium deposition and the effect of preconditioning

In situ observation of magnesium deposition and the effect of preconditioning

File(s)
Zhang_cornell_0058O_10350.pdf (1.65 MB)
Permanent Link(s)
https://doi.org/10.7298/X41J980T
https://hdl.handle.net/1813/59790
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Cornell Theses and Dissertations
Author
Zhang, Kaihang
Abstract

The property free of dendrite enables magnesium a potential candidate for next generation rechargeable metal anode battery. However, due to limited understanding on interfacial transportation of magnesium, stagnant progress is made in terms of high surface impedance, compatible cathode material and etc. Herein, we systematically examine the relationship between current density and magnesium deposition in diffusion-limited region by introducing the concept of over-limiting current. To evaluate, we develop a set of method to regulate the morphology of the magnesium and propose a possible scheme of magnesium deposition mechanism which is proved by Sand’s formula and the result of in-situ observation. Most interestingly, a dendritic morphology of magnesium deposition is detected for first time during observation.

Date Issued
2018-08-30
Keywords
dendrite
•
iodine
•
over limiting current
•
magnesium
•
Chemical engineering
Committee Chair
Archer, Lynden A.
Committee Member
Joo, Yong L.
Degree Discipline
Chemical Engineering
Degree Name
M.S., Chemical Engineering
Degree Level
Master of Science
Type
dissertation or thesis

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