Cornell University
Library
Cornell UniversityLibrary

eCommons

Help
Log In(current)
  1. Home
  2. Cornell University Graduate School
  3. Cornell Theses and Dissertations
  4. Studies of (1) Suppression of electroconvection by porous interphases and polymer additives; and (2) Transient rheology of particle filled polymeric liquids

Studies of (1) Suppression of electroconvection by porous interphases and polymer additives; and (2) Transient rheology of particle filled polymeric liquids

File(s)
Mukherjee_cornellgrad_0058F_15068.pdf (17.78 MB)
Permanent Link(s)
https://doi.org/10.7298/z4c6-x984
https://hdl.handle.net/1813/120931
Collections
Cornell Theses and Dissertations
Author
Mukherjee, Ankush
Abstract

During the charging of a battery cell, electroconvection enhances the growth of non-planar deposits and reduces the life of the battery. We study two mechanisms by which electroconvection can be suppressed without significantly altering bulk electrolyte properties. First, we consider a rigid porous medium adjacent to the ion-selective surface and show that electroconvection can be effectively suppressed when the porous layer occupies most of the thin space charge layer, for a sufficiently small pore size. We also consider a scenario where polymers dissolved in the electrolyte are attracted to the metal electrode due to potential forces of attraction. The potential forces (such as van der Waals forces) acting on the dissolved polymers act as a restoring body force that opposes convective motions that disturb the polymer layer. The flow of particle--laden polymeric fluids has several industrial applications. We use numerical simulations to analyze the rheology of dilute suspensions of spheres and high aspect ratio spheroids (fibers). We study the transient rheology of a suspension of fibers when subjected to steady shear, as well as the rheology of a suspension of spheres in time varying imposed flows. We show that adding particles can reduce the transient extensional stress for large values of the extension rate.

Description
212 pages
Date Issued
2025-08
Keywords
Batteries
•
Dendrites
•
Electroconvection
•
Polymers
•
Pre-shear
•
Suspensions
Committee Chair
Koch, Donald
Committee Member
Desjardins, Olivier
Archer, Lynden
Degree Discipline
Mechanical Engineering
Degree Name
Ph. D., Mechanical Engineering
Degree Level
Doctor of Philosophy
Rights
Attribution 4.0 International
Rights URI
https://creativecommons.org/licenses/by/4.0/
Type
dissertation or thesis

Site Statistics | Help

About eCommons | Policies | Terms of use | Contact Us

copyright © 2002-2026 Cornell University Library | Privacy | Web Accessibility Assistance